Product ID:(TOLUENE, METHYLBENZENE) TX0735S
MSDS Date:08/24/1988
FSC:6810
NIIN:00N018305
MSDS Number: BLWPW

EM SCIENCE

480 DEMOCRAT RD
GIBBSTOWN, NJ 08027
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 609-354-9200

Cage: DO242

EM SCIENCE, A DIVISION OF EM INDUSTRIES

70 GIBBSTOWN, NJ 08027 US

Telephone: 856-423-6300

Cage: 0GDF9

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:LD50: ORL(RAT) 5000 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INGEST: HARMFUL OR FATAL IF SWALLOWED.
INHAL: VAPOR IS HARMFUL IF INHALED. SYMPTOMS: HEADACHE, DIZZINESS,
HALLUCINATIONS, DISTORTED PERCEPTIONS, CHANGES IN MOTOR ACTIVITY,
NAUSEA, DIARRHEA, RESPIRATOR Y IRRITATION, CNS DEPRESSION,
UNCONSCIOUSNESS, LIVER, KIDNEY & LUNG DAMAGE. EYE: CONTACT CAN
CAUSE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: IRRITATION. SKIN: MAY CAUSE
IRRITATION.
Medical Cond Aggravated by Exposure:RESPIRATORY, LIVER AND KIDNEY
CONDITIONS.

First Aid:GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. EYES:
IMMEDIATELY FLUSH THOROUGHLY W/WATER FOR A MINIMUM OF 15 MINUTES.
SKIN: WASH THOROUGHLY WITH SOAP & WATER. INHAL: REMOVE TO FRESH
AIR; GIVE ARTIFICIAL RESPIRATION IF BREATHING HASSTOPPED. INGEST:
CALL MD IMMEDIATELY. ONLY INDUCE VOMITING AT THE INSTRUCTIONS OF
MD. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.

Flash Point Method:TCC
Flash Point:40.0F,4.4C
Lower Limits:1.3%
Upper Limits:7.1%
Extinguishing Media:DRY CHEMICAL, FOAM, CO2, WATER SPRAY TO COOL
EXPOSED CONTAINERS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:VAPOR CAN TRAVEL DISTANCE TO IGNITION
SOURCE & FLASH BACK. DANGEROUS FIRE AND EXPLOSION HAZARD.

Spill Release Procedures:ELIMINATE IGNITION SOURCES; TAKE UP WITH
ABSORBENT. CONTAINERIZE FOR PROPER DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE IN A COOL
AREA AWAY FROM IGNITION SOURCES AND OXIDIZERS.
Other Precautions:DO NOT BREATHE VAPOR OR SOLUTION MIST. DO NOT GET IN
EYES, ON SKIN OR ON CLOTHING. RETAINED RESIDUE MAY MAKE EMPTY
CONTRS HAZARDOUS; USE CAUTION! ELECTRICALLY GROUND ALL EQUIPMENT
WHEN HANDLING THIS P RODUCT. DO NOT TAKE INTERNALLY.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR SHOULD BE WORN IN
THE ABSENCE OF ADEQUATE VENTILATION.
Ventilation:MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED
FUME HOOD OR WITH ADEQUATE VENTILATION.
Protective Gloves:VITON/POLYURETHANE GLOVES OR EQUIVALENT.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH & SAFETY EQUIPMENT SHOULD BE
READILY AVAILABLE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
TESTS ON LABORATORY ANIMALS INDICATE THAT MATERIAL MAY PRODUCE ADVERSE
MUTAGENIC AND REPRODUCTIVE EFFECTS.

HCC:F3
Boiling Pt:B.P. Text:231F,111C
Melt/Freeze Pt:M.P/F.P Text:-139F,-95C
Vapor Pres:21.86 @20C
Vapor Density:3.2
Spec Gravity:0.866
Evaporation Rate & Reference:2.24 (BUTYL ACETATE=1)
Solubility in Water:INSOLUBLE.
Appearance and Odor:CLEAR, COLORLESS LIQUID; AROMATIC ODOR.
Percent Volatiles by Volume:99+

Stability Indicator/Materials to Avoid:YES
OXIDIZERS.
Stability Condition to Avoid:HEAT; CONTACT WITH IGNITION SOURCE.
Hazardous Decomposition Products:COX, HYDROCARBONS.

Waste Disposal Methods:TO BE PERFORMED IN COMPLIANCE WITH ALL CURRENT
LOCAL, STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.